2017 |
Aliaga, J A; Zepeda, T N; Pawelec, B N; Araya, J F; Antunez-Garcia, J; Farias, M H; Fuentes, S; Galvan, D; Alonso-Nunez, G; González, G Microspherical Res2 as a High-Performance Hydrodesulfurization Catalyst Artículo de revista Catalysis Letters, 147 (5), pp. 1243-1251, 2017, ISSN: 1011-372x. Resumen | Enlaces | BibTeX | Etiquetas: carbon, catalysis, composites, dichalcogenides, disulfide, evolution, heterogeneous hidrodesulfurization, hydrodeoxygenation, hydrogen molybdenum-disulfide, nanoparticles, nanosized rhenium solvothermal sulfide, sulfides, synthesis, technetium transition-metal @article{RN349, title = {Microspherical Res2 as a High-Performance Hydrodesulfurization Catalyst}, author = { J.A. Aliaga and T.N. Zepeda and B.N. Pawelec and J.F. Araya and J. Antunez-Garcia and M.H. Farias and S. Fuentes and D. Galvan and G. Alonso-Nunez and G. Gonz\'{a}lez}, url = {/brokenurl#<Go to ISI>://WOS:000400356200016}, doi = {10.1007/s10562-017-2024-6}, issn = {1011-372x}, year = {2017}, date = {2017-01-01}, journal = {Catalysis Letters}, volume = {147}, number = {5}, pages = {1243-1251}, abstract = {An unsupported microspherical ReS2 catalyst, consisting in self-assembled nano-layers, was evaluated in the hydrodesulfurization (HDS) of 3-methylthiophene showing an excellent catalytic activity. The samples were characterized by X-ray diffraction, scanning electron microscopy, high resolution electron microscopy, energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy. These techniques revealed that the rhenium disulfide layers are confined to a 3D hierarchical structure with different stacking, slab size and bending, according to the annealing temperature (400 or 800 A degrees C). The presence of a defect-rich structure in the microspheres, with short and randomly-orientated ReS2 slabs, results in the exposure of additional edge sites, which improve the catalytic performance of this material. This microspherical ReS2 composite, with good HDS performance, is a promising catalyst for the desulfurization of fuel oils; the solvothermal reaction conditions are also useful to tune and create exotic morphologies for the design of new ReS2 catalysts.}, keywords = {carbon, catalysis, composites, dichalcogenides, disulfide, evolution, heterogeneous hidrodesulfurization, hydrodeoxygenation, hydrogen molybdenum-disulfide, nanoparticles, nanosized rhenium solvothermal sulfide, sulfides, synthesis, technetium transition-metal}, pubstate = {published}, tppubtype = {article} } An unsupported microspherical ReS2 catalyst, consisting in self-assembled nano-layers, was evaluated in the hydrodesulfurization (HDS) of 3-methylthiophene showing an excellent catalytic activity. The samples were characterized by X-ray diffraction, scanning electron microscopy, high resolution electron microscopy, energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy. These techniques revealed that the rhenium disulfide layers are confined to a 3D hierarchical structure with different stacking, slab size and bending, according to the annealing temperature (400 or 800 A degrees C). The presence of a defect-rich structure in the microspheres, with short and randomly-orientated ReS2 slabs, results in the exposure of additional edge sites, which improve the catalytic performance of this material. This microspherical ReS2 composite, with good HDS performance, is a promising catalyst for the desulfurization of fuel oils; the solvothermal reaction conditions are also useful to tune and create exotic morphologies for the design of new ReS2 catalysts. |
2013 |
Lopez-Vergara, F; Galdámez, A; Manriquez, V Electrical Behavior of a Cu2fe0.4co0.6sns4 Ceramic Artículo de revista Journal of the Chilean Chemical Society, 58 (4), pp. 2131-2135, 2013, ISSN: 0717-9707. Resumen | Enlaces | BibTeX | Etiquetas: crystals, dielectric quaternary relaxation, solar-cells, solid-solutions, stannite stannite, sulfides @article{RN148, title = {Electrical Behavior of a Cu2fe0.4co0.6sns4 Ceramic}, author = { F. Lopez-Vergara and A. Gald\'{a}mez and V. Manriquez}, url = {/brokenurl#<Go to ISI>://WOS:000331238800047}, doi = {10.4067/S0717-97072013000400051}, issn = {0717-9707}, year = {2013}, date = {2013-01-01}, journal = {Journal of the Chilean Chemical Society}, volume = {58}, number = {4}, pages = {2131-2135}, abstract = {The solid solutions Cu2Fe1-XCoXSnS4, with stannite-type structure are stable up to about 800 degrees C. The electrical properties of the Cu2Fe0.4Co0.6SnS4 ceramic were investigated by complex impedance. The real and imaginary dielectric permittivity dependence with the temperature were measured between 10kHz and 1 MHz in temperature range 77-280K, finding that the ceramic present the characteristics behavior of a dielectric relaxation between 100 and 250 K, with a maximum at approximately 200 K. The electric permittivity found has orders of magnitude between 102 and 103. A space charge polarization mechanism is suggested to explain the observed electric relaxation.}, keywords = {crystals, dielectric quaternary relaxation, solar-cells, solid-solutions, stannite stannite, sulfides}, pubstate = {published}, tppubtype = {article} } The solid solutions Cu2Fe1-XCoXSnS4, with stannite-type structure are stable up to about 800 degrees C. The electrical properties of the Cu2Fe0.4Co0.6SnS4 ceramic were investigated by complex impedance. The real and imaginary dielectric permittivity dependence with the temperature were measured between 10kHz and 1 MHz in temperature range 77-280K, finding that the ceramic present the characteristics behavior of a dielectric relaxation between 100 and 250 K, with a maximum at approximately 200 K. The electric permittivity found has orders of magnitude between 102 and 103. A space charge polarization mechanism is suggested to explain the observed electric relaxation. |
2017 |
Microspherical Res2 as a High-Performance Hydrodesulfurization Catalyst Artículo de revista Catalysis Letters, 147 (5), pp. 1243-1251, 2017, ISSN: 1011-372x. |
2013 |
Electrical Behavior of a Cu2fe0.4co0.6sns4 Ceramic Artículo de revista Journal of the Chilean Chemical Society, 58 (4), pp. 2131-2135, 2013, ISSN: 0717-9707. |