Perez-Mendez, C; Contreras, R Quantitative Characterization of the Global Philicity Patterns of Common Diene/Dienophile Pairs in Cycloaddition Reactions Ii: The Interacting Pair Model Artículo de revista Tetrahedron Letters, 56 (14), pp. 1767-1770, 2015, ISSN: 0040-4039. Resumen | Enlaces | BibTeX | Etiquetas: amines, charge cycloaddition, diels-alder electronegativity, electrophilicity, hardness, mechanism, michael nucleophilicity, reactions, reactivity @article{RN272,
title = {Quantitative Characterization of the Global Philicity Patterns of Common Diene/Dienophile Pairs in Cycloaddition Reactions Ii: The Interacting Pair Model},
author = { C. Perez-Mendez and R. Contreras},
url = {/brokenurl#<Go to ISI>://WOS:000351790700004},
doi = {10.1016/j.tetlet.2015.01.199},
issn = {0040-4039},
year = {2015},
date = {2015-01-01},
journal = {Tetrahedron Letters},
volume = {56},
number = {14},
pages = {1767-1770},
publisher = {2015 Elsevier Ltd.},
abstract = {We present a unified model of electrophilicity and nucleophilicity that considers the electrophile/nucleophile pair in an interacting regime, thereby avoiding the arbitrariness of defining them as the opposite ends of a unique reactivity scale. The model is validated against rate coefficients for the cycloaddition of azomethine ylides towards substituted acetylenes and Michael addition of a series of 1-(X-substituted pheny1)-2-propyn-1-ones towards hydrazine.},
keywords = {amines, charge cycloaddition, diels-alder electronegativity, electrophilicity, hardness, mechanism, michael nucleophilicity, reactions, reactivity},
pubstate = {published},
tppubtype = {article}
}
We present a unified model of electrophilicity and nucleophilicity that considers the electrophile/nucleophile pair in an interacting regime, thereby avoiding the arbitrariness of defining them as the opposite ends of a unique reactivity scale. The model is validated against rate coefficients for the cycloaddition of azomethine ylides towards substituted acetylenes and Michael addition of a series of 1-(X-substituted pheny1)-2-propyn-1-ones towards hydrazine. |