González-Suarez, M; Aizman, A; Soto-Delgado, J; Contreras, R Bond Fukui Functions as Descriptor of the Electron Density Reorganization in Pi Conjugated Systems Artículo de revista Journal of Organic Chemistry, 77 (1), pp. 90-95, 2012, ISSN: 0022-3263. Resumen | Enlaces | BibTeX | Etiquetas: characterization, cycloaddition diels-alder electrophilicity, hardness molecules, quantitative reactions, reactivity, regioselectivity @article{RN108,
title = {Bond Fukui Functions as Descriptor of the Electron Density Reorganization in Pi Conjugated Systems},
author = { M. Gonz\'{a}lez-Suarez and A. Aizman and J. Soto-Delgado and R. Contreras},
url = {/brokenurl#<Go to ISI>://WOS:000298827600008},
doi = {10.1021/jo201465g},
issn = {0022-3263},
year = {2012},
date = {2012-01-01},
journal = {Journal of Organic Chemistry},
volume = {77},
number = {1},
pages = {90-95},
abstract = {The bond Fukui function is introduced and tested as a new reactivity index capable of predicting the evolution of bond breaking and formation processes during an organic reaction involving pi conjugated systems. As an illustration, we examine many cases where substituted ethylenes and dienes may respond to different reagents to yield cycloaddition, Michael addition, and other reactions at double bonds.},
keywords = {characterization, cycloaddition diels-alder electrophilicity, hardness molecules, quantitative reactions, reactivity, regioselectivity},
pubstate = {published},
tppubtype = {article}
}
The bond Fukui function is introduced and tested as a new reactivity index capable of predicting the evolution of bond breaking and formation processes during an organic reaction involving pi conjugated systems. As an illustration, we examine many cases where substituted ethylenes and dienes may respond to different reagents to yield cycloaddition, Michael addition, and other reactions at double bonds. |
