Moris, S; Galdámez, A; Jara, P; Saitz-Barria, C Synthesis of Novel P-Tert-Butylcalix[4]Arene Derivative: Structural Characterization of a Methanol Inclusion Compound Artículo de revista Crystals, 6 (9), 2016, ISSN: 2073-4352. Resumen | Enlaces | BibTeX | Etiquetas: calix[4]arene, crystal crystal-structure structure, synthesis @article{RN310,
title = {Synthesis of Novel P-Tert-Butylcalix[4]Arene Derivative: Structural Characterization of a Methanol Inclusion Compound},
author = { S. Moris and A. Gald\'{a}mez and P. Jara and C. Saitz-Barria},
url = {/brokenurl#<Go to ISI>://WOS:000384529800014},
doi = {10.3390/cryst6090114},
issn = {2073-4352},
year = {2016},
date = {2016-01-01},
journal = {Crystals},
volume = {6},
number = {9},
abstract = {A p-tertbutylcalix[4]arene derivative was synthesized from a reaction of the diisothiocyanate p-tertbutylcalix[4]arene, obtaining crystals that were then characterized by mass spectroscopy, Raman spectroscopy, and single-crystal X-ray diffraction. The molecule presents two acid carbamothioic-n-ethoxy-methyl-ester substituent groups. Through crystallization of this compound, it was also found that it includes a methanol molecule within the aromatic cavity. The inclusion of the methanol molecule is due to favorable CH center dot center dot center dot pi interactions.},
keywords = {calix[4]arene, crystal crystal-structure structure, synthesis},
pubstate = {published},
tppubtype = {article}
}
A p-tertbutylcalix[4]arene derivative was synthesized from a reaction of the diisothiocyanate p-tertbutylcalix[4]arene, obtaining crystals that were then characterized by mass spectroscopy, Raman spectroscopy, and single-crystal X-ray diffraction. The molecule presents two acid carbamothioic-n-ethoxy-methyl-ester substituent groups. Through crystallization of this compound, it was also found that it includes a methanol molecule within the aromatic cavity. The inclusion of the methanol molecule is due to favorable CH center dot center dot center dot pi interactions. |
