2015 |
Celis, F; Campos-Vallette, M; Vega, J C; Gomez-Jeria, J S; Aliaga, C Raman and Surface Enhanced Raman Signals of the Sensor 1-(4-Mercaptophenyl)-2,4,6-Triphenylpyridinium Perchlorate Artículo de revista Journal of the Chilean Chemical Society, 60 (2), pp. 2944-2948, 2015, ISSN: 0717-9707. Resumen | Enlaces | BibTeX | Etiquetas: density dft dyes, dynamics, eht halochromism, hydrocarbons, perchlorate, raman, scattering, sers, shiners, silver, solvent spectroscopy @article{RN261, title = {Raman and Surface Enhanced Raman Signals of the Sensor 1-(4-Mercaptophenyl)-2,4,6-Triphenylpyridinium Perchlorate}, author = { F. Celis and M. Campos-Vallette and J.C. Vega and J.S. Gomez-Jeria and C. Aliaga}, url = {/brokenurl#<Go to ISI>://WOS:000361545700018}, doi = {10.4067/S0717-97072015000200018}, issn = {0717-9707}, year = {2015}, date = {2015-01-01}, journal = {Journal of the Chilean Chemical Society}, volume = {60}, number = {2}, pages = {2944-2948}, abstract = {The sensor 1-(4-mercaptophenyl)-2,4,6-triphenylpyridinium perchlorate compound was vibrationally characterized using Raman and the Surface-Enhanced Raman techniques, SERS and Shell-Isolated Nanoparticles-Enhanced Raman Spectroscopy (SHINERS). The Raman spectrum was analyzed and the band assignment was supported using DFT data at the B3LYP/6-31G(d) level. SERS data allowed infer about the orientation of the analyte on the naked Ag surface. EHT calculations for an Ag/analyte model represent well the SERS spectrum supporting the Ag-S bond formation. The SHINERS spectrum was obtained by using Ag @SiO2 nanoparticles prepared at two different time of the SiO2 coating process. The most intense SHINERS spectral signals of the compound (100 nM) were obtained after 20 minutes of the Ag @SiO2 formation. No charge-transfer was concluded from the SHINERS experiments.}, keywords = {density dft dyes, dynamics, eht halochromism, hydrocarbons, perchlorate, raman, scattering, sers, shiners, silver, solvent spectroscopy}, pubstate = {published}, tppubtype = {article} } The sensor 1-(4-mercaptophenyl)-2,4,6-triphenylpyridinium perchlorate compound was vibrationally characterized using Raman and the Surface-Enhanced Raman techniques, SERS and Shell-Isolated Nanoparticles-Enhanced Raman Spectroscopy (SHINERS). The Raman spectrum was analyzed and the band assignment was supported using DFT data at the B3LYP/6-31G(d) level. SERS data allowed infer about the orientation of the analyte on the naked Ag surface. EHT calculations for an Ag/analyte model represent well the SERS spectrum supporting the Ag-S bond formation. The SHINERS spectrum was obtained by using Ag @SiO2 nanoparticles prepared at two different time of the SiO2 coating process. The most intense SHINERS spectral signals of the compound (100 nM) were obtained after 20 minutes of the Ag @SiO2 formation. No charge-transfer was concluded from the SHINERS experiments. |
2013 |
Seguel, R J; Mancilla, C; Rondanelli, R; Leiva, M A; Morales, R G E Ozone Distribution in the Lower Troposphere over Complex Terrain in Central Chile Artículo de revista Journal of Geophysical Research-Atmospheres, 118 (7), pp. 2966-2980, 2013, ISSN: 2169-897x. Resumen | Enlaces | BibTeX | Etiquetas: boundary-layer, california, chemistry, chile, environmental chemistry, evolution, hydrocarbons, layer, metropolitan-area, model organic-compounds, ozone, ozonesondes, photochemical planetary residual santiago, smog, volatile @article{RN160, title = {Ozone Distribution in the Lower Troposphere over Complex Terrain in Central Chile}, author = { R.J. Seguel and C. Mancilla and R. Rondanelli and M.A. Leiva and R.G.E. Morales}, url = {/brokenurl#<Go to ISI>://WOS:000319618300021}, doi = {10.1002/jgrd.50293}, issn = {2169-897x}, year = {2013}, date = {2013-01-01}, journal = {Journal of Geophysical Research-Atmospheres}, volume = {118}, number = {7}, pages = {2966-2980}, abstract = {Observations were performed in 12 communities of Central Chile in order to determine the horizontal gradients of ozone in the Santiago Basin and surrounding valleys. Higher ozone mixing ratios were found northeast of the Santiago Basin and included east of the Aconcagua Valley (similar to 70km from Santiago) suggesting that photochemical pollution produced in Santiago is capable of passing through the Chacabuco mountain chain (similar to 1.3km) and have impact downwind from the regions with the largest NOx and VOC emissions. To complement existing surface observations, ozonesonde and tethersonde campaigns were performed in the Santiago Basin and the Aconcagua Valley. The results suggest ozone can accumulate in layers aloft (e.g., >102ppb at 2km) similarly to layers observed in complex topography coastal regions like Southern California. Layers of significant ozone concentrations having a near surface origin were observed above the mixed layer and below the subsidence inversion base. We propose that the ozone in this residual layer can be transported large distances (at least to 70km) to further penetrate into the local environment under conditions of a well-mixed boundary layer.}, keywords = {boundary-layer, california, chemistry, chile, environmental chemistry, evolution, hydrocarbons, layer, metropolitan-area, model organic-compounds, ozone, ozonesondes, photochemical planetary residual santiago, smog, volatile}, pubstate = {published}, tppubtype = {article} } Observations were performed in 12 communities of Central Chile in order to determine the horizontal gradients of ozone in the Santiago Basin and surrounding valleys. Higher ozone mixing ratios were found northeast of the Santiago Basin and included east of the Aconcagua Valley (similar to 70km from Santiago) suggesting that photochemical pollution produced in Santiago is capable of passing through the Chacabuco mountain chain (similar to 1.3km) and have impact downwind from the regions with the largest NOx and VOC emissions. To complement existing surface observations, ozonesonde and tethersonde campaigns were performed in the Santiago Basin and the Aconcagua Valley. The results suggest ozone can accumulate in layers aloft (e.g., >102ppb at 2km) similarly to layers observed in complex topography coastal regions like Southern California. Layers of significant ozone concentrations having a near surface origin were observed above the mixed layer and below the subsidence inversion base. We propose that the ozone in this residual layer can be transported large distances (at least to 70km) to further penetrate into the local environment under conditions of a well-mixed boundary layer. |
2015 |
Raman and Surface Enhanced Raman Signals of the Sensor 1-(4-Mercaptophenyl)-2,4,6-Triphenylpyridinium Perchlorate Artículo de revista Journal of the Chilean Chemical Society, 60 (2), pp. 2944-2948, 2015, ISSN: 0717-9707. |
2013 |
Ozone Distribution in the Lower Troposphere over Complex Terrain in Central Chile Artículo de revista Journal of Geophysical Research-Atmospheres, 118 (7), pp. 2966-2980, 2013, ISSN: 2169-897x. |